¹³C Chemical shifts and ¹³C-¹⁵N coupling constants of some ¹⁵N‐labelled bridgehead nitro compounds

Simple item page
dc.contributor.authorDella, E.W.
dc.contributor.authorJanowski, W.K.
dc.contributor.authorKasum, B.
dc.contributor.authorKirkbride, P.K.
dc.contributor.authorShirley, N.J.
dc.date.issued1992
dc.description.abstractMeasurement of the ¹³C NMR spectra of the bridgehead nitro compounds 1a–5a has been performed. It is found that one‐bond ¹³C-¹⁵N coupling is not necessarily a reflection of the degree of s character of the bridgehead carbon exocyclic bonding orbital. Although the magnitude of vicinal coupling to the bridgehead carbon increases, in accordance with the number of three‐bond pathways available for transmission of spin information, coupling is actually reduced by opposing contributions from through‐space intramolecular orbital interactions.
dc.description.statementofresponsibilityErnest W. Della, Wit K. Janowski, Bruno Kasum, K. Paul Kirkbride, and Neil J. Shirley
dc.identifier.citationHeteroatom Chemistry, 1992; 3(1):33-36
dc.identifier.doi10.1002/hc.520030107
dc.identifier.issn1042-7163
dc.identifier.issn1098-1071
dc.identifier.orcidShirley, N.J. [0000-0001-8114-9891]
dc.identifier.urihttp://hdl.handle.net/2440/124525
dc.language.isoen
dc.publisherWiley
dc.rights© 1992 VCH Publishers, Inc.
dc.source.urihttps://doi.org/10.1002/hc.520030107
dc.title¹³C Chemical shifts and ¹³C-¹⁵N coupling constants of some ¹⁵N‐labelled bridgehead nitro compounds
dc.title.alternative13C Chemical shifts and 13C-15N coupling constants of some 15N-labelled bridgehead nitro compounds
dc.typeJournal article
pubs.publication-statusPublished

Files

Collections

Agriculture, Food and Wine publications