Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes

Subashani, M.; Cieslinski, M.; Lincoln, S.; Onagi, H.; Steel, P.; Willis, A.; Easton, C.

doi:10.1021/ol8002145

Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes

Date

2008

Authors

Subashani, M.

Cieslinski, M.

Lincoln, S.

Onagi, H.

Steel, P.

Willis, A.

Easton, C.

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Journal article

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Organic Letters, 2008; 10(10):1885-1888

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Subashani Maniam, Marta M. Cieslinski, Stephen F. Lincoln, Hideki Onagi, Peter J. Steel, Anthony C. Willis and Christopher J. Easton

DOI

10.1021/ol8002145

Abstract

Cyclodextrin [2]rotaxanes have been prepared by coupling dimethylanilines with dicarboxylic acids using DMT-MM, in aqueous solutions of alpha-cyclodextrin, and the example illustrated shows unusual fluorescence emission and other spectroscopic behavior characteristic of the formation of molecular wires in solution, similar to the fibers observed in the solid state.

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https://doi.org/10.1021/ol8002145

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http://hdl.handle.net/2440/51818

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Molecular fibers and wires in solid-state and solution self-assemblies of cyclodextrin [2]rotaxanes

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