Self-sorting of porous Cu₄L₂L′₂ metal–organic cages composed of isomerisable ligands
Date
2021
Authors
Markwell-Heys, A.W.
Schneider, M.L.
Madridejos, J.M.L.
Metha, G.F.
Bloch, W.M.
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Journal article
Citation
Chemical Communications, 2021; 57(23):2915-2918
Statement of Responsibility
Adrian W. Markwell-Heys, Matthew L. Schneider, Jenica Marie L. Madridejos, Gregory F. Metha and Witold M. Bloch
Conference Name
Abstract
We report the self-sorting of a dynamic combinatorial library (DCL) of metal–organic cages composed of a rotationally isomerisable ligand. Convergence of the DCL occurs upon crystallisation and leads to low-symmetry Cu₄L₂L′₂ cages that display differing porosities based on their overall shape and ligand configuration.
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This journal is © The Royal Society of Chemistry 2021.