Picosecond time-resolved photoelectron spectroscopy as a means of elucidating mechanisms of intramolecular vibrational energy redistribution in electronically excited states of small aromatic molecules

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dc.contributor.authorKing, A.
dc.contributor.authorBellm, S.
dc.contributor.authorHammond, C.
dc.contributor.authorReid, K.
dc.contributor.authorTowrie, M.
dc.contributor.authorMatousek, P.
dc.date.issued2005
dc.descriptionAvailable online: 04 Mar 2011
dc.description.abstractPreliminary findings are reported following the detailed analysis of intramolecular vibrational energy redistribution (IVR) in S1 para-fluorotoluene following the excitation of one quantum in the CF stretching mode ν7. It is shown that the method proposed has the potential to enable not only the determination of a rate constant for IVR, but also the identification of the dark states into which energy has redistributed. In addition energy flow has been observed from a bright state (111) previously thought to be below the onset for IVR in this molecule, and evidence of mode-specificity in the IVR process.
dc.description.statementofresponsibilityAdrian K. King, Susan M. Bellm, Chris J. Hammond, Katharine L. Reid, Michael Towrie and Pavel Matousek
dc.identifier.citationMolecular Physics: An International Journal at the Interface Between Chemistry and Physics, 2005; 103(13):1821-1827
dc.identifier.doi10.1080/00268970500096103
dc.identifier.issn0026-8976
dc.identifier.issn1362-3028
dc.identifier.urihttp://hdl.handle.net/2440/56112
dc.language.isoen
dc.publisherTaylor & Francis Ltd
dc.rights© 2005 Taylor & Francis Group Ltd
dc.source.urihttps://doi.org/10.1080/00268970500096103
dc.titlePicosecond time-resolved photoelectron spectroscopy as a means of elucidating mechanisms of intramolecular vibrational energy redistribution in electronically excited states of small aromatic molecules
dc.typeJournal article
pubs.publication-statusPublished

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