Nitrogen-doped CNx/CNTs heteroelectrocatalysts for highly efficient dye-sensitized solar cells

Date

2017

Authors

Shrestha, A.
Batmunkh, M.
Shearer, C.
Yin, Y.
Andersson, G.
Shapter, J.
Qiao, S.
Dai, S.

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Journal article

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Advanced Energy Materials, 2017; 7(8):1602276-1-1602276-8

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Aabhash Shrestha, Munkhbayar Batmunkh, Cameron J. Shearer, Yanting Yin, Gunther G. Andersson, Joseph G. Shapter, Shizhang Qiao, and Sheng Dai

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Abstract

The use of polydopamine as a nitrogen containing precursor to generate catalytically active nitrogen-doped carbon (CNx) materials on carbon nanotubes (CNTs) is reported. These N-doped CNx/CNT materials display excellent electrocatalytic activity toward the reduction of triiodide electrolyte in dye-sensitized solar cells (DSSCs). Further, the influence of various synthesis parameters on the catalytic performance of CNx/CNTs is investigated in detail. The best performing device fabricated with the CNx/CNTs material delivers power conversion efficiency of 7.3%, which is comparable or slightly higher than that of Pt (7.1%) counter electrode-based DSSC. These CNx/CNTs materials show great potential to address the issues associated with the Pt electrocatalyst including the high cost and scarcity.

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© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim

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