A 3-D diamondoid MOF catalyst based on in situ generated [Cu(L)2] N-heterocyclic carbene (NHC) linkers: hydroboration of CO₂
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(Accepted version)
Date
2014
Authors
Burgun, A.
Crees, R.
Cole, M.
Doonan, C.
Sumby, C.
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Chemical Communications, 2014; 50(79):11760-11763
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Alexandre Burgun, Rachel S. Crees, Marcus L. Cole, Christian J. Doonan and Christopher J. Sumby
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Abstract
A new MOF, [Zn4O{Cu(L)2}2] (1), with a 4-fold interpenetrated 3D diamondoid structure was synthesised from in situ generated [Cu(L)2] NHC linkers. MOF 1 possesses tetrahedral Zn4O nodes, which are unusually coordinated by four pairs of carboxylates from four [Cu(L)2] linkers, and 14 A 1-D pore channels lined with [Cu(L)2] moieties that catalyse the hydroboration of CO2.
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Includes supplementary information
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This journal is © The Royal Society of Chemistry 2014