Sonochemical synthesis and characterization of the new plate-shaped lead(II)-iodo coordination polymer: a precursor to produce a pure phase nano-sized lead(II) oxide

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dc.contributor.authorMirtamizdoust, B.
dc.contributor.authorShaabani, B.
dc.contributor.authorKhandar, A.
dc.contributor.authorPourradi, H.
dc.contributor.authorAbbasityula, Y.
dc.contributor.authorGoudarziafshar, H.
dc.contributor.authorViterbo, D.
dc.contributor.authorCroce, G.
dc.contributor.authorHojati-Talemi, P.
dc.date.issued2012
dc.description.abstractPreparation of plate-shaped nanostructures of a new 1D polymeric lead(II) complex containing the Pb2-(μ-I)2 motif, [Pb(neo)I2] n ,(1) where neo is the abbreviation of neocuproine, using a sonochemical method is described. The new coordination polymer is characterized by scanning electron microscopy, X-ray diffraction (XRD), elemental analysis and infrared spectroscopy. The single crystalline material is obtained using a heat gradient applied to a solution of the reagents. Single-crystal XRD analysis indicates that a coordination number of six for PbII ions, (i.e., PbN2I4) with an asymmetrical coordination sphere and “stereo-chemically active” electron lone pairs. They also show that the chains interact with each other through π–π stacking interactions creating a 3D framework. PbO nanoparticles are obtained by thermolysis of 1 at 180 °C with oleic acid as a surfactant. Scanning electron microscopy confirms formation of PbO particles with a size of ~25 nm.
dc.description.statementofresponsibilityBabak Mirtamizdoust, Behrouz Shaabani, Aliakbar Khandar, Hadi Pourradi, Yunes Abbasityula, Hamid Goudarziafshar, Davide Viterbo, Gianluca Croce, Pejman Hojati-Talemi
dc.identifier.citationJournal of Inorganic and Organometallic Polymers and Materials, 2012; 22(6):1293-1299
dc.identifier.doi10.1007/s10904-012-9754-0
dc.identifier.issn1574-1443
dc.identifier.issn1574-1451
dc.identifier.urihttp://hdl.handle.net/2440/89473
dc.language.isoen
dc.publisherSpringer Verlag
dc.rights© Springer Science+Business Media, LLC 2012
dc.source.urihttps://doi.org/10.1007/s10904-012-9754-0
dc.subjectLead(II)
dc.subjectNano coordination polymer
dc.subjectPlate-shape
dc.subjectNano oxide
dc.titleSonochemical synthesis and characterization of the new plate-shaped lead(II)-iodo coordination polymer: a precursor to produce a pure phase nano-sized lead(II) oxide
dc.typeJournal article
pubs.publication-statusPublished

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