Facile insertion of CO2 into metal-phenoxide bonds

Date

2013

Authors

Elmas, S.
Subhani, M.A.
Vogt, H.
Leitner, W.
Muller, T.

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Journal article

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Green Chemistry, 2013; 15(5):1356-1360

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Abstract

The activation of CO2 is highlighted for two lead-structures of cobalt- and zinc-based homogeneous catalysts used in the copolymerization of epoxides and CO2. Following the activation of CO2 with in situ ATR-IR spectroscopy, a surprisingly facile insertion of CO2 into metal–phenoxide bonds was revealed.

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Data source: Supplementary data, http://pubs.rsc.org/en/Content/ArticleLanding/2013/GC/c3gc40147b#!divAbstract Link to a related website: https://pure.mpg.de/pubman/item/item_1854562_1/component/file_1854561/c3gc40147b.pdf, Open Access via Unpaywall

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Copyright 2013 The Authors

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