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Substituent Effects on Ru₃C₂ Clusters: Structural Comparisons of Some μ3-Arylethynyl triruthenium-carbonyl Clusters, [Ru₃(μ-X)(μ₃-C₂Ar)(Y₂)(CO)₇], X = H, or Au(PPh₃), Y₂ = μ-dppm or (CO)₂

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dc.contributor.authorBruce, M.
dc.contributor.authorGaudio, M.
dc.contributor.authorSkelton, B.
dc.contributor.authorWerth, A.
dc.contributor.authorWhite, A.
dc.date.issued2008
dc.description.abstract<jats:title>Abstract</jats:title><jats:p>Complexes of the form [Ru<jats:sub>3</jats:sub>(μ‐H)(μ<jats:sub>3</jats:sub>‐C<jats:sub>2</jats:sub>X)(μ‐dppm)(CO)<jats:sub>7</jats:sub>] have been widely characterized structurally for diverse R = H, <jats:sup>t</jats:sup>Bu, CMePh(OH), CPhCH<jats:sub>2</jats:sub>, C<jats:sub>5</jats:sub>H<jats:sub>7</jats:sub>, C<jats:sub>5</jats:sub>H<jats:sub>6</jats:sub>Me, C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>, as well as being studied theoretically. The R = Ph derivative was found to be isotypic with its C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub> analogue, presenting an unusual opportunity for a comparative structural study, both structures being (re‐)determined at ‘low’‐temperature, whereupon the unit cell of the Ph derivative was found to double. The structure of [AuRu<jats:sub>3</jats:sub>(μ‐C<jats:sub>2</jats:sub>C<jats:sub>6</jats:sub>F<jats:sub>5</jats:sub>)(CO)<jats:sub>9</jats:sub>(PPh<jats:sub>3</jats:sub>)] is also recorded.</jats:p>
dc.description.statementofresponsibilityMichael I. Bruce, Maryka Gaudio, Brian W. Skelton, Anja Werth and Allan H. White
dc.identifier.citationZeitschrift fuer Anorganische und Allgemeine Chemie, 2008; 634(6-7):1106-1110
dc.identifier.doi10.1002/zaac.200800022
dc.identifier.issn0044-2313
dc.identifier.issn1521-3749
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]
dc.identifier.urihttp://hdl.handle.net/2440/51874
dc.language.isoen
dc.publisherWiley-V C H Verlag GMBH
dc.source.urihttps://doi.org/10.1002/zaac.200800022
dc.subjectCluster compounds
dc.subjectCrystal structure
dc.subjectSubstituent effects
dc.subjectGold
dc.subjectCarbonyl complexes
dc.titleSubstituent Effects on Ru₃C₂ Clusters: Structural Comparisons of Some μ3-Arylethynyl triruthenium-carbonyl Clusters, [Ru₃(μ-X)(μ₃-C₂Ar)(Y₂)(CO)₇], X = H, or Au(PPh₃), Y₂ = μ-dppm or (CO)₂
dc.title.alternativeSubstituent effects on Ru3C2 clusters: Structural comparisons of some mu(3)-arylethynyl triruthenium-carbonyl clusters, [Ru-3(mu-X)(mu(3)-C2Ar)(Y-2)(CO)(7)], X = H, or Au(PPh3), Y-2 =mu-dppm or (CO)(2)
dc.typeJournal article
pubs.publication-statusPublished

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