Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series

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dc.contributor.authorBabarao, R.
dc.contributor.authorCoghlan, C.
dc.contributor.authorRankine, D.
dc.contributor.authorBloch, W.
dc.contributor.authorGransbury, G.
dc.contributor.authorSato, H.
dc.contributor.authorKitagawa, S.
dc.contributor.authorSumby, C.
dc.contributor.authorHill, M.
dc.contributor.authorDoonan, C.
dc.date.issued2014
dc.description.abstractThe effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption
dc.description.statementofresponsibilityRavichandar Babarao, Campbell J. Coghlan, Damien Rankine, Witold M. Bloch, Gemma K. Gransbury, Hiroshi Sato, Susumu Kitagawa, Christopher J. Sumby, Matthew R. Hill and Christian J. Doonan
dc.identifier.citationChemical Communications, 2014; 50(24):3238-3241
dc.identifier.doi10.1039/C4CC00700J
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.orcidCoghlan, C. [0000-0003-1625-3216]
dc.identifier.orcidBloch, W. [0000-0003-1084-1287]
dc.identifier.orcidSumby, C. [0000-0002-9713-9599]
dc.identifier.urihttp://hdl.handle.net/2440/81958
dc.language.isoen
dc.publisherRoyal Soc Chemistry
dc.relation.granthttp://purl.org/au-research/grants/arc/FT100100400
dc.relation.granthttp://purl.org/au-research/grants/arc/FT0991910
dc.rightsCopyright status unknown
dc.source.urihttps://doi.org/10.1039/c4cc00700j
dc.titleDoes functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
dc.title.alternativeDoes functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
dc.typeJournal article
pubs.publication-statusPublished

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