Studies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1 2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy

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dc.contributor.authorBos, R.
dc.contributor.authorBarnett, N.
dc.contributor.authorDyson, G.
dc.contributor.authorLim, K.
dc.contributor.authorRussell, R.
dc.contributor.authorWatson, S.
dc.date.issued2004
dc.descriptionCopyright © 2003 Elsevier B.V. All rights reserved.
dc.description.abstractA simple model peroxyoxalate chemiluminescence system was monitored directly across a range of temperatures (from −80 to +20 °C) using 13C nuclear magnetic resonance spectroscopy. These experiments were made possible by the utilisation of 13C doubly labelled oxalyl chloride, which was reacted with anhydrous hydrogen peroxide in dry tetrahydrofuran. Ab initio quantum calculations were also performed to estimate the 13C nuclear magnetic resonance (NMR) shift of the most commonly postulated key intermediate 1,2-dioxetanedione and this data, in concert with the spectroscopic evidence, confirmed its presence during the reaction.
dc.description.statementofresponsibilityRichard Bos, Neil W. Barnett, Gail A. Dyson, Kieran F. Lim, Richard A. Russell and Simon P. Watson
dc.identifier.citationAnalytica Chimica Acta, 2004; 502(2):141-147
dc.identifier.doi10.1016/j.aca.2003.10.014
dc.identifier.issn0003-2670
dc.identifier.urihttp://hdl.handle.net/2440/48128
dc.language.isoen
dc.publisherElsevier Science BV
dc.source.urihttps://doi.org/10.1016/j.aca.2003.10.014
dc.subjectPeroxyoxalate chemiluminescence intermediate
dc.subject1,2-Dioxetanedione
dc.subjectNuclear magnetic resonance spectroscopy
dc.subjectAb initio quantum calculations
dc.titleStudies on the mechanism of the peroxyoxalate chemiluminescence reaction Part 1. Confirmation of 1 2-dioxetanedione as an intermediate using 13C nuclear magnetic resonance spectroscopy
dc.typeJournal article
pubs.publication-statusPublished

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