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Reactions between ruthenium cluster carbonyls and 1, 4-diphenylbuta-1,3-diyne

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dc.contributor.authorBruce, M.
dc.contributor.authorZaitseva, N.
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.date.issued1996
dc.descriptionCopyright © 1996 Published by Elsevier Science B.V.
dc.description.abstractThe complexes RuC(Ctriple bond; length as m-dashCPh)=CPhC(Ctriple bond; length as m-dashCPh)=CPh(CO)3(NMe3) (3), Ru2μ-C(Ctriple bond; length as m-dashCPh)=CPhC(Ctriple bond; length as m-dashCPh)=CPh(CO)6 (1), Ru2μ-[C(Ctriple bond; length as m-dashCPh)=CPh]2CO(CO)6 (2), Ru3(μ3-PhC2Ctriple bond; length as m-dashCPh)(μ-CO)(CO)9 (4) and Ru4(μ4-PhC2Ctriple bond; length as m-dashCPh)(CO)12 (5) have been isolated from reactions between PhC2C2Ph and Ru3(CO)12 or RU3(CO)10(NCMe)2. The molecular structures of complexes 1, 2, 3 and 5 have been determined from single-crystal X-ray studies. All complexes have precedents in similar products obtained from reactions involving mono-ynes; in the present cases, each alkyne fragment retains a phenylethynyl (PhCtriple bond; length as m-dashC---) group as a non-coordinated substituent.
dc.description.urihttp://www.elsevier.com/wps/find/journaldescription.cws_home/504086/description#description
dc.identifier.citationInorganica Chimica Acta, 1996; 250(2):129-138
dc.identifier.doi10.1016/S0020-1693(96)05219-X
dc.identifier.issn0020-1693
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]
dc.identifier.urihttp://hdl.handle.net/2440/4499
dc.language.isoen
dc.publisherElsevier BV
dc.source.urihttps://doi.org/10.1016/s0020-1693(96)05219-x
dc.subjectCrystal structures
dc.subjectRuthenium complexes
dc.subject1,3-Diyne complexes
dc.subjectCarbonyl complexes
dc.subjectCluster complexes
dc.titleReactions between ruthenium cluster carbonyls and 1, 4-diphenylbuta-1,3-diyne
dc.typeJournal article
pubs.publication-statusPublished

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