Λ-{1,4,7,10-Tetrakis[(S)-2-hydroxypropyl-κO]-1,4,7,10-tetraazacyclododecane-κ4N}cadmium(II) bis(2,4,6-trinitrophenolate) acetonitrile solvate
| dc.contributor.author | Smith, C. | |
| dc.contributor.author | Lincoln, S. | |
| dc.contributor.author | Taylor, M. | |
| dc.contributor.author | Wainwright, K. | |
| dc.date.issued | 2003 | |
| dc.description.abstract | Crystallization of [Cd(S-thpc12)](ClO4)2·H2O {S-thpc12 is 1,4,7,10-tetrakis[(S)-2-hydroxypropyl]-1,4,7,10-tetraazacyclododecane} in the presence of two equivalents of sodium picrate monohydrate (sodium 2,4,6-trinitrophenolate monohydrate) diastereoselectively produces a neutral receptor complex, viz. the title compound, Λ-[Cd(C20H44N4O4)](C6H2N3O7)2·CH3CN. In this complex, two picrate anions hydrogen bond, via their phenolate moieties, to the pendant hydroxyl groups of the receptor which, together with the four N atoms, themselves bond to CdII in an approximately cubic arrangement. One picrate anion hydrogen bonds to all four hydroxyl groups, one of which also acts as the sole hydrogen-bond donor to the second picrate anion. | |
| dc.description.statementofresponsibility | Christopher B. Smith, Stephen F. Lincoln, Max R. Taylor and Kevin P. Wainwright | |
| dc.identifier.citation | Acta Crystallographica Section C: Crystal Structure Communications, 2003; 59(9):M358-M360 | |
| dc.identifier.doi | 10.1107/S0108270103016007 | |
| dc.identifier.issn | 0108-2701 | |
| dc.identifier.issn | 1600-5759 | |
| dc.identifier.uri | http://hdl.handle.net/2440/17908 | |
| dc.language.iso | en | |
| dc.publisher | Blackwell Munksgaard | |
| dc.rights | © 2003 International Union of Crystallography | |
| dc.source.uri | http://onlinelibrary.wiley.com/doi/10.1107/S0108270103016007/abstract | |
| dc.title | Λ-{1,4,7,10-Tetrakis[(S)-2-hydroxypropyl-κO]-1,4,7,10-tetraazacyclododecane-κ4N}cadmium(II) bis(2,4,6-trinitrophenolate) acetonitrile solvate | |
| dc.title.alternative | Lambda-{1,4,7,10-Tetrakis[(S)-2-hydroxypropyl-kappaO]-1,4,7,10-tetraazacyclododecane-kappa4N}cadmium(II) bis(2,4,6-trinitrophenolate) acetonitrile solvate | |
| dc.type | Journal article | |
| pubs.publication-status | Published |