Effect of BN(h) and Si₃N₄ reinforcement content on the morphology and properties of Ni-W coatings

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2023

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Gbenontin, B.V.
Kang, M.
Ndumia, J.N.
Nyambura, S.M.
Awuah, E.
Jitao, L.
Anhua, R.

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Journal of Materials Engineering and Performance, 2023; 32(18):8401-8418

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Ni-W-BN(h)-Si₃N₄ nanocomposite coatings were deposited on AISI 1045 steel using a traditional electrodeposition technique. The effects of BN(h) and Si₃N₄ nanoparticles on the performance of the coatings were investigated. Varying concentrations of Si₃N₄ nanoparticles were added to the bath of Ni-W-BN(h) nanocomposite coatings having an optimized concentration of BN(h) nanoparticles. The electrodeposited coatings were characterized using a laser scanning confocal microscope tester, scanning electron microscope, energy dispersive spectroscopy, x-ray diffraction, Vickers microhardness, and high-frequency reciprocating CFT-1 wear tester. The results indicated that the peaks of the coatings were ascribed to (111) of FCC nickel-based solid solution. Ni, W, B, Si, and N elements were uniformly distributed in the coating. Ni-W-BN(h) coating fabricated with 6 g/L of BN(h) presented a hardness of 680.98 HV₀.₀₂₅ and a wear rate of 2.53 × 10⁻⁶ mm³·N⁻¹m⁻¹. Ni-W-BN(h) composite coating's microhardness and wear resistance were improved by maintaining the BN(h) concentration at 6 g/L and raising the Si₃N₄ concentration to 6 g/L. Ni-W-BN(h)-Si₃N₄ coating fabricated with 12 g/L of (BN(h) + Si₃N₄) presented the best microhardness (722.86 HV₀.₀₂₅) and wear rate (2.08 × 10⁻⁶ mm³·N⁻¹m⁻¹). The wear mechanisms of all coatings were studied.

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Copyright 2022 Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

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