Bronze alloys with tin surface sites for selective electrochemical reduction of CO₂
Date
2018
Authors
Vasileff, A.
Xu, C.
Ge, L.
Zheng, Y.
Qiao, S.
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Journal article
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Chemical Communications, 2018; 54(99):13965-13968
Statement of Responsibility
Anthony Vasileff, Chaochen Xu, Lei Ge, Yao Zheng and Shi-Zhang Qiao
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Abstract
Low concentration tin bronze alloys show high selectivity for CO2 electroreduction to CO, while high concentration tin bronze alloys show high selectivity for formate. The tin surface sites appear to control selectivity by influencing the binding characteristics toward the first reaction intermediate on copper-based alloys.
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This journal is ©The Royal Society of Chemistry 2018.