Asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol
Date
2013
Authors
Ferrer, C.
Fodran, P.
Barroso, S.
Gibson, R.
Hopmans, E.
Damsté, J.
Schouten, S.
Minnaard, A.
Editors
Advisors
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Journal article
Citation
Organic and Biomolecular Chemistry, 2013; 11(15):2482-2492
Statement of Responsibility
Catalina Ferrer, Peter Fodran, Santiago Barroso, Robert Gibson, Ellen C. Hopmans, Jaap Sinninghe Damsté, Stefan Schouten and Adriaan J. Minnaard
Conference Name
Abstract
An efficient asymmetric synthesis of cyclo-archaeol and β-glucosyl cyclo-archaeol is presented employing catalytic asymmetric conjugate addition and catalytic epoxide ring opening as the key steps. Their occurrence in deep sea hydrothermal vents has been confirmed by chromatographic comparison with natural samples.
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This journal is © The Royal Society of Chemistry 2013