Selected-control synthesis and the phase transition of Fe3O 4 and a-FeOOH in ethanol/water media

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2006

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Jia, B.
Gao, L.

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Journal of The American Ceramic Society, 2006; 89(5):1739-1741

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<jats:p> <jats:bold> Fe <jats:sub>3</jats:sub> O <jats:sub>4</jats:sub> nanoparticles and α‐FeOOH nanorods with tunable size have been selected control synthesized via a facile hydrothermal process in the presence of CTAB. By means of adjusting the volume ratio of ethanol/water media at three levels: 0 (in which water was used as a solvent alone), 2:3, and 4:1, phases of the products transformed from Fe <jats:sub>3</jats:sub> O <jats:sub>4</jats:sub> into α‐FeOOH gradually. X‐ray powder diffraction, transmission electron microscopy, and energy‐dispersive X‐ray spectroscopy were used to characterize the as‐synthesized samples. The related mechanisms of phase transformation are discussed. </jats:bold> </jats:p>

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