Novel crown ether assemblies: the role of isobenzofurans for attaching crown ethers to rigid molecular racks in a geometrically precise fashion
Date
1997
Authors
Warrener, R.N.
Wang, S.D.
Russell, R.A.
Gunter, M.J.
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Journal article
Citation
Synlett, 1997; 1997(1):47-50
Statement of Responsibility
Ronald N. Warrener, Shudong Wang, Richard A. Russell, Maxwell J. Gunter
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Abstract
Rigid polyalicyclic nanostructures with extended and U-shaped geometry and functionalised with 15-crown-5 rings have been prepared from molrac mono or bisalkenes and new crown ether isobenzofurans; substituents in the 1,3-position of the isobenzofuran are used to modify stereospecifities in the cycloaddition process thereby acting as geometrical control agents in the construction process.
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© Georg Thieme Verlag