Synthesis, Characterization and X-ray Structures of Diphenyltin(IV) N-(2-Hydroxyacetophenone)glycinate, Its 1:1 Adduct with Triphenyltin(IV) Chloride, and Related Systems
Date
1998
Authors
Dakternieks, Dainis
Basu Baul, Tushar S.
Dutta, Sushmita
Tiekink, Edward Richard Tom
Editors
Advisors
Journal Title
Journal ISSN
Volume Title
Type:
Journal article
Citation
Organometallics, 1998; 17(14):3058-3062
Statement of Responsibility
Dainis Dakternieks, Tushar S. Basu Baul, Sushmita Dutta and Edward R. T. Tiekink
Conference Name
Abstract
The compound [Ph2Sn(2-OC6H4C(CH3)NCH2COO)], 1, shows a distorted trigonal-bipyramidal geometry in the solid state. Reaction of 1 with Ph3SnCl yields a 1:1 adduct in which the two tin atoms are joined via the carbonyl atom of the ligand in 1 to form a mixed diorgano/triorgano species. NMR data indicate that the 1:1 adduct dissociates in noncoordinating solvent. Similarly, [tBu2Sn(2-OC6H4C(CH3)NCH2COO)·tBu2SnCl2], which has been characterized crystallographically in the solid state, is dissociated in solution. In contrast to the above behavior, monomeric [Vin2Sn(2-OC6H4C(CH3)NCH2COO)] forms an adduct with a water molecule to yield [Vin2Sn(2-OC6H4C(CH3)NCH2COO)OH2] in the solid state.
School/Discipline
School of Chemistry and Physics
Dissertation Note
Provenance
Description
Copyright © 1998 American Chemical Society