Strategies and methods for the attachment of amino acids and peptides to chiral [n]polynorbornane templates

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2003

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Pfeffer, F.
Russell, R.

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Organic and Biomolecular Chemistry, 2003; 1(11):1845-1851

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A versatile synthesis of amino acid and peptide functionalised [n]polynorbornane scaffolds is described. The frameworks are constructed using the stereoselective and regioselective cycloaddition of suitably functionalisedchiral cyclobutene epoxides with similar norbornenes. The strategies employed allow a range of topologies to be accessed and a number of regioselectively addressable linkage points to be accommodated.

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© The Royal Society of Chemistry 2003

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