Synthesis of the putative structure of tridachiahydropyrone
dc.contributor.author | Jeffery, D. | |
dc.contributor.author | Perkins, M. | |
dc.contributor.author | White, J. | |
dc.date.issued | 2005 | |
dc.description.abstract | [reaction: see text] A short total synthesis of the putative structure of the marine natural product tridachiahydropyrone as a single enantiomer is described. Novel steps include a cuprate addition and cyclization to form a cyclohexanone ring and formation of the bicyclic pyrone with P(2)O(5) on Celite. The spectroscopic data obtained for compound 1 do not match those reported for tridachiahydropyrone; therefore, revision of the assigned natural product structure is warranted. | |
dc.description.statementofresponsibility | David W. Jeffery, Michael V. Perkins, and Jonathan M. White | |
dc.identifier.citation | Organic Letters, 2005; 7(8):1581-1584 | |
dc.identifier.doi | 10.1021/ol050236d | |
dc.identifier.issn | 1523-7060 | |
dc.identifier.issn | 1523-7052 | |
dc.identifier.orcid | Jeffery, D. [0000-0002-7054-0374] | |
dc.identifier.uri | http://hdl.handle.net/2440/66396 | |
dc.language.iso | en | |
dc.publisher | Amer Chemical Soc | |
dc.rights | Copyright © 2005 American Chemical Society | |
dc.source.uri | https://doi.org/10.1021/ol050236d | |
dc.subject | Animals | |
dc.subject | Mollusca | |
dc.subject | Pyrones | |
dc.subject | Nuclear Magnetic Resonance, Biomolecular | |
dc.subject | Molecular Structure | |
dc.subject | Cyclization | |
dc.subject | Stereoisomerism | |
dc.title | Synthesis of the putative structure of tridachiahydropyrone | |
dc.type | Journal article | |
pubs.publication-status | Published |