Use of modulators and light to control crystallisation of a hydrogen bonded framework
Date
2022
Authors
Muang-Non, P.
Toop, H.D.
Doonan, C.J.
White, N.G.
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Chemical Communications, 2022; 58(2):306-309
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Phonlakrit Muang-Non, Hamish D. Toop, Christian J. Doonan and Nicholas G. White
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Abstract
The effect of concentration, organic co-solvent, and salt modulators on the crystallisation of a hydrogen bonded framework was studied. The framework contains ∼1.4 nm wide channels and contains a diazobenzene based dicarboxylate anion. Light-induced <i>cis</i>/<i>trans</i> switching of this anion was also used to control crystallisation.
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This journal is © The Royal Society of Chemistry 2022