Mechanism of acetal cleavage with methylmagnesium iodide

Simple item page
dc.contributor.authorAbell, A.D.
dc.contributor.authorMassywestropp, R.A.
dc.date.issued1985
dc.description.abstractThe reaction of methylmagnesium iodide with methyl (1R,3S,5R)-1-(furan- 3′-yl)-5-methyl-2,8-dioxabicyclo[3.2.1]octane-3-carboxylate (2) gives products arising from regioselective carbon-oxygen bond fission and intermolecular transfer of the methyl group of the Grignard reagent to the intermediate oxocarbonium ion, in addition to the usual tertiary alcohol.
dc.description.statementofresponsibilityAD Abell and RA Massy-Westropp
dc.identifier.citationAustralian Journal of Chemistry: an international journal for chemical science, 1985; 38(7):1031-1036
dc.identifier.doi10.1071/CH9851031
dc.identifier.issn0004-9425
dc.identifier.issn1445-0038
dc.identifier.orcidAbell, A.D. [0000-0002-0604-2629]
dc.identifier.urihttp://hdl.handle.net/2440/86625
dc.language.isoen
dc.publisherCSIRO Publishing
dc.rights© CSIRO 1985
dc.source.urihttp://dx.doi.org/10.1071/ch9851031
dc.titleMechanism of acetal cleavage with methylmagnesium iodide
dc.typeJournal article
pubs.publication-statusPublished

Files

Collections

Chemistry publications