A Percyanovinylidene−Ruthenium Complex, Ru{═C═C₅(CN)₃[═C(CN)₂]₂}(dppe)Cp*

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dc.contributor.authorBruce, M.
dc.contributor.authorMorris, J.
dc.contributor.authorNicholson, B.
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.contributor.authorZaitseva, N.
dc.date.issued2011
dc.description.abstractThe reaction between Ru(C=CC=CAg)(dppe)Cp* and tcne affords a novel percyanovinylidene complex by an unusual decyano-dimerization reaction of the cyanocarbon with the diynyl fragment. This complex is also obtained from tcne and Ru{C=CC=C[Au(PPh<inf>3</inf>)]}(dppe)Cp*, together with Ru{C=CC[=C(CN)<inf>2</inf>]C[Au(PPh<inf>3</inf>)]=C(CN)<inf>2</inf>}(dppe)Cp *, formed by the anticipated [2 + 2] cycloaddition and subsequent ring-opening reactions. © 2011 American Chemical Society.
dc.description.statementofresponsibilityMichael I. Bruce, Jonathan C. Morris, Brian K. Nicholson, Brian W. Skelton, Allan H. White, and Natasha N. Zaitseva
dc.identifier.citationOrganometallics, 2011; 30(3):653-656
dc.identifier.doi10.1021/om1010885
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]
dc.identifier.urihttp://hdl.handle.net/2440/71120
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.relation.grantARC
dc.rightsCopyright © 2011 American Chemical Society
dc.source.urihttps://doi.org/10.1021/om1010885
dc.titleA Percyanovinylidene−Ruthenium Complex, Ru{═C═C₅(CN)₃[═C(CN)₂]₂}(dppe)Cp*
dc.title.alternativeA Percyanovinylidene -Ruthenium Complex, Ru{=C=C(5)(CN)(3)[=C(CN)(2)](2)}(dppe)Cp*
dc.typeJournal article
pubs.publication-statusPublished

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