Metal-metal interactions in correlated single-atom catalysts

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dc.contributor.authorShan, J.
dc.contributor.authorYe, C.
dc.contributor.authorJiang, Y.
dc.contributor.authorJaroniec, M.
dc.contributor.authorZheng, Y.
dc.contributor.authorQiao, S.-Z.
dc.date.issued2022
dc.description.abstractSingle-atom catalysts (SACs) include a promising family of electrocatalysts with unique geometric structures. Beyond conventional ones with fully isolated metal sites, an emerging class of catalysts with the adjacent metal single atoms exhibiting intersite metal-metal interactions appear in recent years and can be denoted as correlated SACs (C-SACs). This type of catalysts provides more opportunities to achieve substantial structural modification and performance enhancement toward a wider range of electrocatalytic applications. On the basis of a clear iden-tification of metal-metal interactions, this review critically examines the recent research progress in C-SACs. It shows that the control of metal-metal interactions enables regulation of atomic structure, local coordination, and electronic properties of metal single atoms, which facilitate the modulation of electrocatalytic behavior of C-SACs. Last, we outline directions for future work in the design and development of C-SACs, which is indispensable for creating high-performing new SAC architectures.
dc.description.statementofresponsibilityJieqiong Shan, Chao Ye, Yunling Jiang, Mietek Jaroniec, Yao Zheng, Shi-Zhang Qiao
dc.identifier.citationScience Advances, 2022; 8(17)
dc.identifier.doi10.1126/sciadv.abo0762
dc.identifier.issn2375-2548
dc.identifier.issn2375-2548
dc.identifier.orcidShan, J. [0000-0003-4308-5027]
dc.identifier.orcidJiang, Y. [0000-0002-7545-2891]
dc.identifier.orcidZheng, Y. [0000-0002-2411-8041]
dc.identifier.orcidQiao, S.-Z. [0000-0002-1220-1761] [0000-0002-4568-8422]
dc.identifier.urihttps://hdl.handle.net/2440/135199
dc.language.isoen
dc.publisherAmerican Association for the Advancement of Science
dc.relation.granthttp://purl.org/au-research/grants/arc/FL170100154
dc.relation.granthttp://purl.org/au-research/grants/arc/FT200100062
dc.relation.granthttp://purl.org/au-research/grants/arc/DP190103472
dc.rightsCopyright © 2022 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC)
dc.source.urihttps://doi.org/10.1126/sciadv.abo0762
dc.titleMetal-metal interactions in correlated single-atom catalysts
dc.typeJournal article
pubs.publication-statusPublished

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