Novel associative polymer networks based on cyclodextrin inclusion compounds

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dc.contributor.authorGuo, X.
dc.contributor.authorAbdala, A.
dc.contributor.authorMay, B.
dc.contributor.authorLincoln, S.
dc.contributor.authorKhan, S.
dc.contributor.authorPrud'homme, R.
dc.date.issued2005
dc.description© 2005 American Chemical Society
dc.description.abstractA new routine to synthesize α- and β-cyclodextrin (CD)-modified PAA and a novel associative polymer networks based on mixture of CD-modified and hydrophobically-modified (HM) poly(acrylic acid) (PAA) were described. It was shown that the inclusion interactions between CD and hydrophobe grafts in PAAs lead to stronger associations and solution viscosities than purely hydrophobic interactions at the same polymer concentration. The cyclodextrin inclusion is strictly binary, and its strength can be tuned by the choice of CD and hydrophobic species. The screening of the association between hydrophobically modified PAA by free α- or β-cyclodextrins occurs at approximately a stoichiometric ratio of cyclodextrin to hydrophobe.
dc.description.statementofresponsibilityXuhong Guo, Ahmed A. Abdala, Bruce L. May, Stephen F. Lincoln, Saad A. Khan, and Robert K. Prud’homme
dc.identifier.citationMacromolecules, 2005; 38(7):3037-3040
dc.identifier.doi10.1021/ma050071o
dc.identifier.issn0024-9297
dc.identifier.issn1520-5835
dc.identifier.urihttp://hdl.handle.net/2440/17930
dc.language.isoen
dc.publisherAmer Chemical Soc
dc.source.urihttps://doi.org/10.1021/ma050071o
dc.titleNovel associative polymer networks based on cyclodextrin inclusion compounds
dc.typeJournal article
pubs.publication-statusPublished

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