Kinetics and mechanism of synergistic adsorption and persulfate activation by N-doped porous carbon for antibiotics removals in single and binary solutions

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dc.contributor.authorTian, W.
dc.contributor.authorLin, J.
dc.contributor.authorZhang, H.
dc.contributor.authorDuan, X.
dc.contributor.authorWang, H.
dc.contributor.authorSun, H.
dc.contributor.authorWang, S.
dc.date.issued2021
dc.description.abstractPorous carbon serves as a green material for efficient wastewater purification by adsorption and advanced oxidation processes. However, a clear understanding of the simultaneous removal of multiple pollutants in water is still ambiguous. Herein, the synergistic effect of adsorption and peroxydisulfate (PS) activation on kinetics and mechanism of removing single and binary antibiotic pollutants, sulfamethoxazole (SMX) and ibuprofen (IBP), from water by biomass-derived N-doped porous carbon was investigated. Our findings suggest that adsorption contributed to efficient removals of SMX/IBP. Comparative quenching experiments and electrochemical analysis demonstrated that hydroxyl (•OH) and sulfate (SO<sub>4</sub><sup>•-</sup>) radicals, as well as singlet oxygen (<sup>1</sup>O<sub>2</sub>) led to the catalytic degradation of SMX, while only <sup>1</sup>O<sub>2</sub> reacted for IBP oxidation. Superoxide ion (O<sub>2</sub><sup>•-</sup>) radicals were not related to SMX/IBP degradation. Electron transfer pathway accounted for PS activation but was not involved in direct SMX/IBP oxidation. Only slight differences were found between the degradation kinetics of SMX and IBP in the binary and single SMX or IBP solutions. This arose from the non-selective effect of adsorption and <sup>1</sup>O<sub>2</sub> attack for SMX/IBP removal, and the weak selective oxidation process of SMX by •OH and SO<sub>4</sub><sup>•-</sup>. This study provides a new viewpoint on the role of adsorption in catalysis and enriches the mechanistic study of multi-component antibiotic degradation.
dc.description.statementofresponsibilityWenjie Tian, Jingkai Lin, Huayang Zhang, Xiaoguang Duan, Hao Wang, Hongqi Sun, Shaobin Wang
dc.identifier.citationJournal of Hazardous Materials, 2021; 423(Pt A):127083-127083
dc.identifier.doi10.1016/j.jhazmat.2021.127083
dc.identifier.issn0304-3894
dc.identifier.issn1873-3336
dc.identifier.orcidTian, W. [0000-0002-7503-5481] [0000-0002-9896-1154]
dc.identifier.orcidLin, J. [0000-0001-6409-0146]
dc.identifier.orcidDuan, X. [0000-0001-9635-5807]
dc.identifier.orcidWang, S. [0000-0002-1751-9162]
dc.identifier.urihttps://hdl.handle.net/2440/134481
dc.language.isoen
dc.publisherElsevier
dc.relation.granthttp://purl.org/au-research/grants/arc/DP190103548
dc.rights© 2021 Elsevier B.V. All rights reserved.
dc.source.urihttps://doi.org/10.1016/j.jhazmat.2021.127083
dc.subjectAdsorption
dc.subjectAdvanced oxidation processes
dc.subjectBinary antibiotic micropollutants
dc.subjectBiomass-derived porous carbon
dc.subjectWater remediation
dc.subject.meshAdsorption
dc.subject.meshAnti-Bacterial Agents
dc.subject.meshCarbon
dc.subject.meshKinetics
dc.subject.meshPorosity
dc.subject.meshWater Pollutants, Chemical
dc.titleKinetics and mechanism of synergistic adsorption and persulfate activation by N-doped porous carbon for antibiotics removals in single and binary solutions
dc.typeJournal article
pubs.publication-statusPublished

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