The synthesis of a dichloroalane complex and its reaction with an alpha-diimine
Date
2008
Authors
Alexander, S.
Cole, M.
Hilder, M.
Morris, J.
Patrick, J.
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Advisors
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Type:
Journal article
Citation
Dalton Transactions, 2008; 2008(45):6361-6363
Statement of Responsibility
Sean G. Alexander, Marcus L. Cole, Matthias Hilder, Jonathan C. Morris and Joanna B. Patrick
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DOI
Abstract
Reaction of an alpha-diimine, {MesN=CH}2 (Mes=2,4,6-trimethylphenyl), with the dichloroalane [AlCl2H(IMes)] (IMes=1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) affords an N-heterocyclic carbene (NHC) transfer complex [AlCl2{MesNC(=IMes)C(H)NMes}] rather than the expected hydroalumination product.
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Dissertation Note
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© Royal Society of Chemistry 2008