An asymmetric intramolecular alkylation to form a bicyclo[3.1.O]hexanone derivative
Date
1988
Authors
Hamon, D.P.
Shirley, N.J.
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Journal article
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Journal of the Chemical Society, Chemical Communications, 1988; (6):425-426
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David P. G. Hamon and Neil J. Shirley
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Abstract
The epoxy ketol (–)-2-hydroxymethyl-1-oxaspiro[2.5]octan-6-one (7b) isomerises with base to 1-(1,2-dihydroxy-1-methylethyl)bicyclo[3.1.0]hexan-4-one (5b) with high diastereoselectivity.
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