An asymmetric intramolecular alkylation to form a bicyclo[3.1.O]hexanone derivative

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1988

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Hamon, D.P.
Shirley, N.J.

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Journal of the Chemical Society, Chemical Communications, 1988; (6):425-426

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David P. G. Hamon and Neil J. Shirley

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Abstract

The epoxy ketol (–)-2-hydroxymethyl-1-oxaspiro[2.5]octan-6-one (7b) isomerises with base to 1-(1,2-dihydroxy-1-methylethyl)bicyclo[3.1.0]hexan-4-one (5b) with high diastereoselectivity.

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