Quantitative formation of core cross-linked star polymers via a one-pot two-step single electron transfer-living radical polymerization
Date
2013
Authors
Wong, E.H.H.
Blencowe, A.
Qiao, G.G.
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Journal article
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Polymer Chemistry, 2013; 4(17):4562-4565
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Abstract
A novel and highly efficient one-pot two-step strategy towards core cross-linked star polymers based on single electron transfer-living radical polymerization (SET-LRP) is described. Macroinitiators with high end-group fidelity were generated at high monomer conversions prior to the addition of cross-linkable monomers in the same pot to induce the formation of star polymers. Quantitative (>99%) star formation is achieved without the purification of unreacted monomers or macroinitiators.
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Data source: supplementary information, https://doi.org/10.1039/C3PY00726J
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Copyright 2013 The Royal Society of Chemistry