Preparation and Structure of [Ru(CO)2(PPh)3(h-C5Me5)][Fe3(m3-C2But)(CO)9]
Date
1998
Authors
Bruce, M.
Zaitseva, N.
Skelton, B.
White, A.
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Journal article
Citation
Australian Journal of Chemistry, 1998; 51(5):433-435
Statement of Responsibility
Michael I. Bruce, Natasha N. Zaitseva, Brian W. Skelton and Allan H. White
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DOI
Abstract
The reaction between RuCl(C=CHBut)(PPh3)(η-C5Me5) and Fe2(CO)9 afforded the salt [Ru(CO)2(PPh3)-(η-C5Me5)] [Fe3(µ3-C2But)(CO)9], which has been characterized by a single-crystal X-ray structure determination. The cation has a piano-stool structure, while the anion contains a CCBut ligand sitting on a triangular Fe3 cluster.
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© CSIRO 1998