Corymbolone
| dc.contributor.author | Burrett, S. | |
| dc.contributor.author | Taylor, D. | |
| dc.contributor.author | Tiekink, E. | |
| dc.date.issued | 2014 | |
| dc.description | Organic compounds. Supporting information is sup-1 to sup-7 | |
| dc.description.abstract | The title compound, C15H24O2 [systematic name: (4S,4aR,6R,8aR)-4a-hy-droxy-4,8a-dimethyl-6-(prop-1-en-2-yl)octahydro-naphthalen-1(2H)-one], features two edge-shared six-membered rings with the hydroxyl and methyl substituents at this bridge being trans. One adopts a flattened chair conformation with the C atoms bearing the carbonyl and methyl substituents lying 0.5227 (16) and 0.6621 (15) Å, respectively, above and below the mean plane through the remaining four C atoms (r.m.s. deviation = 0.0145 Å). The second ring, bearing the prop-1-en-2-yl group, has a chair conformation. Supra-molecular helical chains along the b axis are found in the crystal packing, which are sustained by hy-droxy-carbonyl O-H⋯O hydrogen bonding. | |
| dc.description.statementofresponsibility | Stacey Burrett, Dennis K. Taylor and Edward R. T. Tiekink | |
| dc.identifier.citation | Acta Crystallographica Section E, 2014; 70(7):o758-o758 | |
| dc.identifier.doi | 10.1107/S1600536814012938 | |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.issn | 1600-5368 | |
| dc.identifier.orcid | Taylor, D. [0000-0002-3302-4610] [0000-0002-4274-3983] [0000-0003-0633-7424] | |
| dc.identifier.uri | http://hdl.handle.net/2440/94784 | |
| dc.language.iso | en | |
| dc.publisher | International Union of Crystallography | |
| dc.rights | © International Union of Crystallography. Open Access. | |
| dc.source.uri | https://doi.org/10.1107/s1600536814012938 | |
| dc.title | Corymbolone | |
| dc.type | Journal article | |
| pubs.publication-status | Published |