A high-yielding enantiospecific synthesis of (-)-7-deoxydaunomycinone
Date
1984
Authors
Russell, R.A.
Krauss, A.S.
Warrener, R.N.
Irvine, R.W.
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Journal article
Citation
Tetrahedron Letters, 1984; 25(14):1517-1520
Statement of Responsibility
Richard A. Russell, Adrian S. Krauss, Ronald N. Warrener, Robert W. Irvine
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Abstract
A comparison is made between two regiospecific modes of base-catalysed condensation of 4 (or 7)-methoxy-3-phenylsulfonyl phthalides with chiral bicyclic quinone monoketals, one of which occurs in 95% yield and forms the basis of the first enantiospecific total synthesis of (−)-7-deoxydaunomycinone (3).
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© 1984 Pergamon Press Ltd.