Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols

Date

2006

Authors

Fox, David J.
Pedersen, Daniel Sejer
Petersen, Asger B.
Warren, Stuart

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Journal article

Citation

Organic and Biomolecular Chemistry , 2006; 4 (16):3117-3119

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David J. Fox, Daniel Sejer Pedersen, Asger B. Petersen and Stuart Warren

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Abstract

Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful intermediates in cyclopropane synthesis.

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School of Chemistry and Physics : Chemistry

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© The Royal Society of Chemistry 2006

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