Diphenylphosphinoyl chloride as a chlorinating agent - The selective double activation of 1,2-diols
Date
2006
Authors
Fox, David J.
Pedersen, Daniel Sejer
Petersen, Asger B.
Warren, Stuart
Editors
Advisors
Journal Title
Journal ISSN
Volume Title
Type:
Journal article
Citation
Organic and Biomolecular Chemistry , 2006; 4 (16):3117-3119
Statement of Responsibility
David J. Fox, Daniel Sejer Pedersen, Asger B. Petersen and Stuart Warren
Conference Name
DOI
Abstract
Treatment of 1,2-diols with diphenylphosphinoyl chloride in pyridine produces beta-chloroethyl phosphinates which react with complete control of stereochemistry to give epoxides and azido-alcohols, useful intermediates in cyclopropane synthesis.
School/Discipline
School of Chemistry and Physics : Chemistry
Dissertation Note
Provenance
Description
© The Royal Society of Chemistry 2006