Observation of hot carriers existing in Ag₂S nanoparticles and its implication on solar cell application

Date

2016

Authors

Lin, S.
Feng, Y.
Wen, X.
Harada, T.
Kee, T.
Huang, S.
Shrestha, S.
Conibeer, G.

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Journal article

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The Journal of Physical Chemistry C: Energy Conversion and Storage, Optical and Electronic Devices, Interfaces, Nanomaterials, and Hard Matter, 2016; 120(19):10199-10205

Statement of Responsibility

S. Lin, Y. Feng, X. Wen, T. Harada, T. W. Kee, S. Huang, S. Shrestha and G. Conibeer

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Abstract

Silver sulfide, Ag, S, nanoparticle, NP, is a promising material for quantum-dot-based hot-carrier solar cell, yet the hot carrier dynamics of the material has not been thoroughly studied for this purpose. In this work, carrier cooling dynamics of Ag, S NP thin film were measured and analyzed using the transient absorption, TA, spectrometer. The NPs exhibit a relatively high carrier temperature and long carrier cooling time. This result was further verified by the carrier temperature extraction from steady-state photoluminescence, ssPL, spectrum. The long carrier cooling time in Ag, S NPs can potentially lead to efficiency of 33.6% demonstrating potential application for the high-efficiency hot-carrier solar cell.

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© 2016 American Chemical Society

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