Position-Addressable Nano-Scaffolds. I. The Preparation of N O- N C- and N N-Bridged Sesquinorbornadiene Succinimides as Compact Highly Functionalized Addressable Building Blocks

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dc.contributor.authorWarrener, R.
dc.contributor.authorMargetic, D.
dc.contributor.authorSun, G.
dc.contributor.authorRussell, R.
dc.date.issued2003
dc.description© CSIRO 2003
dc.description.abstractSuccinimide-functionalized N,O-, N,C-, and N,N-bridged benzo[2]polynorbornanes (benzosesquinorbornadienes) are reported for the first time and are prepared by the cycloaddition of either five-membered cyclic 1,3-dienes onto N-substituted benzo-7-azanorbornadienomaleimides or N-substituted isoindoles onto the appropriate norbornadienomaleimides. These products contain an end-fused norbornene (or a 7-substituted relative) and have been designed to act as alkene BLOCKs for the production of nano-scaffolds with up to six addressable sites supplied by each norbornene unit. The N-bridges in these BLOCKs (and their coupled products) allow N-substituent mobility by invertomerization of the sp3 nitrogen whereas the N-substituents on the succinimides are attached to an sp2 nitrogen atom and remain static. Preferred invertomer geometry can be determined using molecular modelling.
dc.description.statementofresponsibilityRonald N. Warrener, Davor Margetic, Guangxing Sun and Richard A. Russell
dc.identifier.citationAustralian Journal of Chemistry, 2003; 56(4):263-267
dc.identifier.doi10.1071/CH02218
dc.identifier.issn0004-9425
dc.identifier.issn1445-0038
dc.identifier.urihttp://hdl.handle.net/2440/48129
dc.language.isoen
dc.publisherC S I R O Publishing
dc.source.urihttp://www.publish.csiro.au/nid/51/paper/CH02218.htm
dc.titlePosition-Addressable Nano-Scaffolds. I. The Preparation of N O- N C- and N N-Bridged Sesquinorbornadiene Succinimides as Compact Highly Functionalized Addressable Building Blocks
dc.typeJournal article
pubs.publication-statusPublished

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