Increased sensitivity in T-ray liquid spectroscopy using rapid sample modulation

Date

2004

Authors

Mickan, S.
Munch, J.
Zhang, X.
Abbott, D.

Editors

Hwu, R.J.

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Conference paper

Citation

Terahertz and gigahertz electronics and photonics III, 25-26 January 2004 / R. Jennifer Hwu (ed.): pp. 71-85

Statement of Responsibility

Samuel P. Mickan, Jesper Munch, Xi-Cheng Zhang, and Derek Abbott

Conference Name

Terahertz and Gigahertz Electronics and Photonics III (2004 : San Jose, California)

Abstract

Pulsed THz (T-ray) spectroscopy is sensitive, non-invasive tool for studying materials from physics to biology, but transmission measurements of liquid samples, especially water, have been limited by noise. This paper shows that the accuracy of T-ray material parameter measurements of liquid samples can be greatly increased, especially for highly-absorbing liquids, by using a rapid modulation of the liquid in the T-ray beam path, coupled with a novel implementation of mean and amplitude detection to T-ray spectroscopy. The experiments are supported by calculations quantifying the sources of uncertainty. Liquid transmission T-ray studies are valuable for understanding solvation dynamics of salts, exploring long-range structure in mixtures and probing biomolecules in suspension.

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© 2004 COPYRIGHT SPIE--The International Society for Optical Engineering

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