Comprehending the effect of MMoO4 (M = Co, Ni) nanoflakes on improving the electrochemical performance of NiO electrodes

Date

2015

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An, L.
Li, W.
Cao, Y.
Xu, K.
Zou, R.
Ji, T.
Yu, L.
Hu, J.

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Dalton Transactions, 2015; 44(48):21131-21140

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Abstract

The design and fabrication of high performance supercapacitors with a high specific capacitance and a long lifespan still remain a challenge. We present two hydrothermal and two annealing processes for the fabrication of hierarchical heterostructures of NiO@MMoO4 (M = Co, Ni) nanosheet arrays on Ni foam. In this hierarchical structure, numerous MMoO4 nanoflakes grow on a NiO nanosheet and the integration of MMoO4 can improve the whole electrode's conductivity, leading to an ideal pathway for electron and ion transport. The hierarchical NiO@MMoO4 (M = Co, Ni) heterostructure electrode demonstrated remarkable electrochemical performance with a high specific capacitance and predominant cycling stability, making it one of the prospective electrode materials for high performance supercapacitors.

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Copyright The Royal Society of Chemistry 2015

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