Catalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide

dc.contributor.authorKantam, M.L.
dc.contributor.authorPriyadarshini, S.
dc.contributor.authorJoseph, P.J.A.
dc.contributor.authorSrinivas, P.
dc.contributor.authorVinu, A.
dc.contributor.authorKlabunde, K.J.
dc.contributor.authorNishina, Y.
dc.date.issued2012
dc.descriptionData source: Supplementary material, http://www.sciencedirect.com/science/MiamiMultiMediaURL/1-s2.0-S0040402012007508/1-s2.0-S0040402012007508-mmc1.doc/271372/html/S0040402012007508/6e2e77bbdc3557f2e8c330ff3d1c4da4/mmc1.doc
dc.description.abstractNanocrystalline ZnO was found to be a highly efficient heterogeneous catalyst for the guanylation of amines with various carbodiimides to afford N,N′,N″-trisubstituted guanidines in excellent yields. Structurally divergent aliphatic, aromatic, heterocyclic primary and secondary amines were converted to the corresponding N,N′,N″-trisubstituted guanidines using optimal conditions. The catalyst was easy to handle even under atmospheric conditions and can be easily recovered by centrifugation and reused for five cycles with consistent activity.
dc.identifier.citationTetrahedron, 2012; 68(29):5730-5737
dc.identifier.doi10.1016/j.tet.2012.05.044
dc.identifier.issn0040-4020
dc.identifier.urihttps://hdl.handle.net/11541.2/116382
dc.language.isoen
dc.publisherElsevier
dc.relation.fundingCSIR New Delhi
dc.relation.fundingNIMS-IICT
dc.relation.fundingUGC India
dc.rightsCopyright 2012 Elsevier
dc.source.urihttps://doi.org/10.1016/j.tet.2012.05.044
dc.subjectguanylation
dc.subjectamines
dc.subjectcarbodiimides
dc.subjectnanocrystalline zinc oxide
dc.subjectheterogeneous catalysis
dc.titleCatalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide
dc.typeJournal article
pubs.publication-statusPublished
ror.mmsid9915985810501831

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