Catalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide
| dc.contributor.author | Kantam, M.L. | |
| dc.contributor.author | Priyadarshini, S. | |
| dc.contributor.author | Joseph, P.J.A. | |
| dc.contributor.author | Srinivas, P. | |
| dc.contributor.author | Vinu, A. | |
| dc.contributor.author | Klabunde, K.J. | |
| dc.contributor.author | Nishina, Y. | |
| dc.date.issued | 2012 | |
| dc.description | Data source: Supplementary material, http://www.sciencedirect.com/science/MiamiMultiMediaURL/1-s2.0-S0040402012007508/1-s2.0-S0040402012007508-mmc1.doc/271372/html/S0040402012007508/6e2e77bbdc3557f2e8c330ff3d1c4da4/mmc1.doc | |
| dc.description.abstract | Nanocrystalline ZnO was found to be a highly efficient heterogeneous catalyst for the guanylation of amines with various carbodiimides to afford N,N′,N″-trisubstituted guanidines in excellent yields. Structurally divergent aliphatic, aromatic, heterocyclic primary and secondary amines were converted to the corresponding N,N′,N″-trisubstituted guanidines using optimal conditions. The catalyst was easy to handle even under atmospheric conditions and can be easily recovered by centrifugation and reused for five cycles with consistent activity. | |
| dc.identifier.citation | Tetrahedron, 2012; 68(29):5730-5737 | |
| dc.identifier.doi | 10.1016/j.tet.2012.05.044 | |
| dc.identifier.issn | 0040-4020 | |
| dc.identifier.uri | https://hdl.handle.net/11541.2/116382 | |
| dc.language.iso | en | |
| dc.publisher | Elsevier | |
| dc.relation.funding | CSIR New Delhi | |
| dc.relation.funding | NIMS-IICT | |
| dc.relation.funding | UGC India | |
| dc.rights | Copyright 2012 Elsevier | |
| dc.source.uri | https://doi.org/10.1016/j.tet.2012.05.044 | |
| dc.subject | guanylation | |
| dc.subject | amines | |
| dc.subject | carbodiimides | |
| dc.subject | nanocrystalline zinc oxide | |
| dc.subject | heterogeneous catalysis | |
| dc.title | Catalytic guanylation of aliphatic, aromatic, heterocyclic primary and secondary amines using nanocrystalline zinc(II) oxide | |
| dc.type | Journal article | |
| pubs.publication-status | Published | |
| ror.mmsid | 9915985810501831 |