Di-tert-butyl (2R,3R)-2-{[(2E)-3-(4-acetyloxy-3-methoxyphenyl)prop-2-enoyl]-oxy}-3-hydroxybutanedioate

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dc.contributor.authorHixson, J.
dc.contributor.authorTaylor, D.
dc.contributor.authorNg, S.
dc.contributor.authorTiekink, E.
dc.date.issued2012
dc.description.abstractIn the title molecule, C₂₄H₃₂O₁₀, one tert-butyl ester group is folded towards the central benzene ring while the other is directed away. The acetyl group is almost perpendicular to the benzene ring to which it is connected [C-C-O-C torsion angle = 90.4 (12)°]. The conformation about the ethene bond [1.313(7)Å] is E. The atoms of the benzene ring and its attached ester group and part of the hydroxy tert-butyl ester side chain are disordered over two sets of sites in a 50:50 ratio. Linear supramolecular chains along the a axis mediated by hydroxy-carbonyl O-H...O hydrogen bonds feature in the crystal packing. The same H atom also partakes in an intramolecular O-H...O interaction.
dc.description.statementofresponsibilityJosh L. Hixson, Dennis K. Taylor, Seik Weng Ng, and Edward R. T. Tiekink
dc.identifier.citationActa Crystallographica Section E: Structure Reports Online, 2012; 68(3):o568-o569
dc.identifier.doi10.1107/S1600536812002784
dc.identifier.issn1600-5368
dc.identifier.issn1600-5368
dc.identifier.orcidTaylor, D. [0000-0002-3302-4610] [0000-0002-4274-3983] [0000-0003-0633-7424]
dc.identifier.urihttp://hdl.handle.net/2440/74730
dc.language.isoen
dc.publisherBlackwell Munksgaard
dc.rightsCopyright © International Union of Crystallography
dc.source.urihttps://doi.org/10.1107/s1600536812002784
dc.titleDi-tert-butyl (2R,3R)-2-{[(2E)-3-(4-acetyloxy-3-methoxyphenyl)prop-2-enoyl]-oxy}-3-hydroxybutanedioate
dc.typeJournal article
pubs.publication-statusPublished

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