Syntheses and crystal structures of some CCo3 clusters containing PPh3 or dppm Ligands
Date
2004
Authors
Bruce, M.
Kramarczuk, K.
Perkins, G.
Skelton, B.
White, A.
Zaitseva, N.
Editors
Advisors
Journal Title
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Volume Title
Type:
Journal article
Citation
Journal of Cluster Science, 2004; 15(2):119-137
Statement of Responsibility
Michael I. Bruce, Kathy A. Kramarczuk, Gary J. Perkins, Brian W. Skelton, Allan H. White and Natasha N. Zaitseva
Conference Name
Abstract
Molecular structural determinations are reported for six Co3C carbonyl cluster complexes containing tertiary phosphines, which have been isolated as by-products from a variety of reactions. Structural features are similar to those of related complexes already reported. Some discussion of apparent orientational preferences of the CH2 group of dppm ligands, which appear to enter into H-bonding interactions with amido or carboxylate substituents, is given. Appropriate comparisons are made with unsubstituted analogues.
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Dissertation Note
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Description
The original publication is available at www.springerlink.com