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https://hdl.handle.net/2440/107086
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Type: | Journal article |
Title: | Mapping-out catalytic processes in a metal-organic framework with single-crystal X-ray crystallography |
Author: | Burgun, A. Coghlan, C. Huang, D. Chen, W. Horike, S. Kitagawa, S. Alvino, J. Metha, G. Sumby, C. Doonan, C. |
Citation: | Angewandte Chemie International Edition, 2017; 56(29):8412-8416 |
Publisher: | Wiley |
Issue Date: | 2017 |
ISSN: | 1433-7851 1521-3773 |
Statement of Responsibility: | Alexandre Burgun, Campbell J. Coghlan, David M. Huang, Wenqian Chen, Satoshi Horike, Susumu Kitagawa, Jason F. Alvino, Gregory F. Metha, Christopher J. Sumby, and Christian J. Doonan |
Abstract: | Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a MnII -based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems. |
Keywords: | carbonylation heterogeneous catalysis MOFs rhodium complexes structure elucidation |
Description: | Version of record online: February 3, 2017 |
Rights: | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
DOI: | 10.1002/anie.201611254 |
Grant ID: | http://purl.org/au-research/grants/arc/DP160103234 |
Published version: | http://dx.doi.org/10.1002/anie.201611254 |
Appears in Collections: | Aurora harvest 3 Chemical Engineering publications |
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