Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/107086
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Type: Journal article
Title: Mapping-out catalytic processes in a metal-organic framework with single-crystal X-ray crystallography
Author: Burgun, A.
Coghlan, C.
Huang, D.
Chen, W.
Horike, S.
Kitagawa, S.
Alvino, J.
Metha, G.
Sumby, C.
Doonan, C.
Citation: Angewandte Chemie - International Edition, 2017; 56(29):8412-8416
Publisher: Wiley
Issue Date: 2017
ISSN: 1433-7851
1521-3773
Statement of
Responsibility: 
Alexandre Burgun, Campbell J. Coghlan, David M. Huang, Wenqian Chen, Satoshi Horike, Susumu Kitagawa, Jason F. Alvino, Gregory F. Metha, Christopher J. Sumby, and Christian J. Doonan
Abstract: Single-crystal X-ray crystallography is employed to characterize the reaction species of a full catalytic carbonylation cycle within a MnII -based metal-organic framework (MOF) material. The structural insights explain why the Rh metalated MOF is catalytically competent toward the carbonylation of MeBr but only affords stoichiometric turn-over in the case of MeI. This work highlights the capability of MOFs to act as platform materials for studying single-site catalysis in heterogeneous systems.
Keywords: carbonylation; heterogeneous catalysis; MOFs; rhodium complexes; structure elucidation
Description: Version of record online: February 3, 2017
Rights: © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
RMID: 0030064022
DOI: 10.1002/anie.201611254
Grant ID: http://purl.org/au-research/grants/arc/DP160103234
Appears in Collections:Chemical Engineering publications

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