Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/34906
Citations | ||
Scopus | Web of Science® | Altmetric |
---|---|---|
?
|
?
|
Type: | Journal article |
Title: | Crystal-packing motifs of [Ag₄L₄]⁴+ star-burst tetrahedra |
Other Titles: | Crystal-packing motifs of [Ag(4)L(4)](4)+ star-burst tetrahedra |
Author: | Sumby, C. Carr, M. Franken, A. Kennedy, J. Kilner, C. Hardie, M. |
Citation: | New Journal of Chemistry: a journal for new directions in chemistry, 2006; 30(10):1390-1396 |
Publisher: | Royal Soc Chemistry |
Issue Date: | 2006 |
ISSN: | 1144-0546 1369-9261 |
Statement of Responsibility: | Christopher J. Sumby, Michael J. Carr, Andreas Franken, John D. Kennedy, Colin A. Kilner and Michaele J. Hardie |
Abstract: | Further examples of a metallo-supramolecular star-burst tetrahedron are reported from reaction of the ligand tris(4-pyridylmethylamino)cyclotriguaiacylene, 1, and AgPF₆ in the presence of dinitrile species, or from reaction of 1 with Ag[1-Ph-closo-1-CB₉H₈-6-I]. Complex [Ag₄(1) ₄(CH₃CN)₃]•4(PF₆)•5(CH₃CN)•(H₂O) has a hexagonal structure where packing of the [Ag₄(1)₄]⁴⁺ tetrahedra mimics the close-packing of spheres. In complex {Ag₄(1)₄(CH₃CN)₂[PhCB₉H₈I]₂}•2[PhCB₉H₈I]•11(CH₃CN) the [1-Ph-closo-1-CB₉H₈-6-I]⁻ anion coordinates to the [Ag₄(1)₄]⁴⁺ tetrahedron through Ag–I and Ag•••H–B interactions, and a less symmetric packing motif is found. The synthesis and crystal structure of the novel monocarbaborane species (NEt₄)[1-Ph-closo-1-CB₉H₈-6-I] are also reported. |
Rights: | © Royal Society of Chemistry 2006 |
DOI: | 10.1039/b609356f |
Published version: | http://dx.doi.org/10.1039/b609356f |
Appears in Collections: | Aurora harvest 6 Chemistry publications Environment Institute publications |
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.