Please use this identifier to cite or link to this item:
https://hdl.handle.net/2440/81958
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Type: | Journal article |
Title: | Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series |
Other Titles: | Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series |
Author: | Babarao, R. Coghlan, C. Rankine, D. Bloch, W. Gransbury, G. Sato, H. Kitagawa, S. Sumby, C. Hill, M. Doonan, C. |
Citation: | Chemical Communications, 2014; 50(24):3238-3241 |
Publisher: | Royal Soc Chemistry |
Issue Date: | 2014 |
ISSN: | 1359-7345 1364-548X |
Statement of Responsibility: | Ravichandar Babarao, Campbell J. Coghlan, Damien Rankine, Witold M. Bloch, Gemma K. Gransbury, Hiroshi Sato, Susumu Kitagawa, Christopher J. Sumby, Matthew R. Hill and Christian J. Doonan |
Abstract: | The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption |
Rights: | Copyright status unknown |
DOI: | 10.1039/C4CC00700J |
Grant ID: | http://purl.org/au-research/grants/arc/FT100100400 http://purl.org/au-research/grants/arc/FT0991910 |
Published version: | http://dx.doi.org/10.1039/c4cc00700j |
Appears in Collections: | Aurora harvest 4 Chemistry publications |
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hdl_81958.pdf | Accepted version | 797.33 kB | Adobe PDF | View/Open |
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