Please use this identifier to cite or link to this item: http://hdl.handle.net/2440/81958
Citations
Scopus Web of Science® Altmetric
?
?
Type: Journal article
Title: Does functionalisation enhance CO₂ uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
Other Titles: Does functionalisation enhance CO2 uptake in interpenetrated MOFs? An examination of the IRMOF-9 series
Author: Babarao, R.
Coghlan, C.
Rankine, D.
Bloch, W.
Gransbury, G.
Sato, H.
Kitagawa, S.
Sumby, C.
Hill, M.
Doonan, C.
Citation: Chemical Communications, 2014; 50(24):3238-3241
Publisher: Royal Soc Chemistry
Issue Date: 2014
ISSN: 1359-7345
1364-548X
Statement of
Responsibility: 
Ravichandar Babarao, Campbell J. Coghlan, Damien Rankine, Witold M. Bloch, Gemma K. Gransbury, Hiroshi Sato, Susumu Kitagawa, Christopher J. Sumby, Matthew R. Hill and Christian J. Doonan
Abstract: The effect of pore functionalisation (-I, -OH, -OCH3) on a series of topologically equivalent, interpenetrated metal-organic frameworks (MOFs) was assessed by both simulation and experiment. Counter-intuitively, a decreased affinity for CO2 was observed in the functionalised materials, compared to the non-functionalised material. This result highlights the importance of considering the combined effects of network topology and chemical functionality in the design of MOFs for enhanced CO2 adsorption
Rights: Copyright status unknown
RMID: 0020135633
DOI: 10.1039/C4CC00700J
Grant ID: http://purl.org/au-research/grants/arc/FT100100400
http://purl.org/au-research/grants/arc/FT0991910
Appears in Collections:Chemistry publications

Files in This Item:
File Description SizeFormat 
hdl_81958.pdfAccepted version797.33 kBAdobe PDFView/Open


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.