Topological control in paddlewheel metal–organic cages via ligand length variation
Date
2024
Authors
Tsoukatos, S.
Maibam, A.
Babarao, R.
Bloch, W.M.
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Journal article
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Chemical Communications, 2024; 60(90):13183-13186
Statement of Responsibility
Steven Tsoukatos, Ashakiran Maibam, Ravichandar Babarao and Witold M. Bloch
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Abstract
Varying the length of phenanthrene-derived ligands switches the selective assembly of MIInLn metal–organic cages (MOCs, n = 6 or 8) between tetrahedral, square, or triangular architectures. The limit of this approach is explored for both Cu2 and Rh2 paddlewheel MOCs, and supported by solution, solid-state and computational analysis.
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© The Royal Society of Chemistry 2024