Biomimetic total synthesis of rhodonoids C and D, and murrayakonine D

Date

2017

Authors

Day, A.
Lamr, H.
Sumby, C.
George, J.

Editors

Advisors

Journal Title

Journal ISSN

Volume Title

Type:

Journal article

Citation

Organic Letters, 2017; 19(10):2463-2465

Statement of Responsibility

Aaron J. Day, Hiu C. Lam, Christopher J. Sumby and Jonathan H. George

Conference Name

DOI

10.1021/acs.orglett.7b00779

Abstract

A divergent, three-step total synthesis of rhodonoids C and D has been achieved using a biosynthetically inspired, acid-catalyzed cascade cyclization of an epoxy-chromene that involves the presumed intermediacy of o-quinone methides. Application of a similar strategy also allowed synthesis of the alkaloid murrayakonine D.

School/Discipline

Dissertation Note

Provenance

Description

Access Status

Rights

© 2017 American Chemical Society

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Grant ID

http://purl.org/au-research/grants/arc/DP160103393

Published Version

https://doi.org/10.1021/acs.orglett.7b00779

Call number

Persistent link to this record

http://hdl.handle.net/2440/105989