Biomimetic total synthesis of rhodonoids C and D, and murrayakonine D

dc.contributor.authorDay, A.
dc.contributor.authorLamr, H.
dc.contributor.authorSumby, C.
dc.contributor.authorGeorge, J.
dc.date.issued2017
dc.description.abstractA divergent, three-step total synthesis of rhodonoids C and D has been achieved using a biosynthetically inspired, acid-catalyzed cascade cyclization of an epoxy-chromene that involves the presumed intermediacy of o-quinone methides. Application of a similar strategy also allowed synthesis of the alkaloid murrayakonine D.
dc.description.statementofresponsibilityAaron J. Day, Hiu C. Lam, Christopher J. Sumby and Jonathan H. George
dc.identifier.citationOrganic Letters, 2017; 19(10):2463-2465
dc.identifier.doi10.1021/acs.orglett.7b00779
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.orcidSumby, C. [0000-0002-9713-9599]
dc.identifier.orcidGeorge, J. [0000-0002-7330-2160]
dc.identifier.urihttp://hdl.handle.net/2440/105989
dc.language.isoen
dc.publisherAmerican Chemical Society
dc.relation.granthttp://purl.org/au-research/grants/arc/DP160103393
dc.rights© 2017 American Chemical Society
dc.source.urihttps://doi.org/10.1021/acs.orglett.7b00779
dc.subjectTerpenes
dc.subjectBenzopyrans
dc.subjectBiomimetics
dc.subjectMolecular Structure
dc.subjectCyclization
dc.subjectStereoisomerism
dc.titleBiomimetic total synthesis of rhodonoids C and D, and murrayakonine D
dc.typeJournal article
pubs.publication-statusPublished

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