Preparation and structure of Ru2(m-O2CCF3)2(CO)4(NCMe)2

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1999

Authors

Bruce, M.
Zaitseva, N.
Skelton, B.
White, A.

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Australian Journal of Chemistry: an international journal for chemical science, 1999; 52(6):621-623

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Michael I. Bruce, Brian W. Skelton, Natasha N. Zaitseva and Allan H. White

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Abstract

The molecular structure of Ru2(µ-O2CCF3)2(CO)4(NCMe)2, obtained from Ru3(CO)10(NCMe)2 and CF3CO2H, or from Ru3(CO)12 and CF3CO2H in a CH2Cl2/MeCN mixture, is presented. The central Ru–Ru bond [2·683(1) Å] is bridged by the two carboxylato ligands [Ru–O (average) 2·133 Å]. Each ruthenium carries mutually cis CO ligands approximately trans to the Ru–O vectors and an MeCN ligand in the axial position [Ru–N (average) 2·18 Å].

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