Preparation and structure of Ru2(m-O2CCF3)2(CO)4(NCMe)2

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dc.contributor.authorBruce, M.
dc.contributor.authorZaitseva, N.
dc.contributor.authorSkelton, B.
dc.contributor.authorWhite, A.
dc.date.issued1999
dc.description.abstractThe molecular structure of Ru2(µ-O2CCF3)2(CO)4(NCMe)2, obtained from Ru3(CO)10(NCMe)2 and CF3CO2H, or from Ru3(CO)12 and CF3CO2H in a CH2Cl2/MeCN mixture, is presented. The central Ru–Ru bond [2·683(1) Å] is bridged by the two carboxylato ligands [Ru–O (average) 2·133 Å]. Each ruthenium carries mutually cis CO ligands approximately trans to the Ru–O vectors and an MeCN ligand in the axial position [Ru–N (average) 2·18 Å].
dc.description.statementofresponsibilityMichael I. Bruce, Brian W. Skelton, Natasha N. Zaitseva and Allan H. White
dc.identifier.citationAustralian Journal of Chemistry: an international journal for chemical science, 1999; 52(6):621-623
dc.identifier.doi10.1071/CH99005
dc.identifier.issn0004-9425
dc.identifier.orcidBruce, M. [0000-0002-8377-7186]
dc.identifier.urihttp://hdl.handle.net/2440/4339
dc.language.isoen
dc.publisherCSIRO Publishing
dc.source.urihttp://www.publish.csiro.au/nid/51/paper/CH99005.htm
dc.titlePreparation and structure of Ru2(m-O2CCF3)2(CO)4(NCMe)2
dc.typeJournal article
pubs.publication-statusPublished

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