Synthesis and preliminary analytical evaluation of the chemiluminescence from (4-[4-(dichloromethylsilanyl)-butyl]-4'-methyl-2 2'-bipyridyl)bis(2 2'-bipyridyl))ruthenium(II) covalently bonded to silica particles
Date
2002
Authors
Barnett, N.
Bos, R.
Brand, H.
Jones, P.
Lim, K.
Purcell, S.
Russell, R.
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Advisors
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Journal article
Citation
The Analyst, 2002; 127(4):455-458
Statement of Responsibility
Neil W. Barnett, Richard Bos, Holger Brand, Philip Jones, Kieran F. Lim, Stuart D. Purcell and Richard A. Russell
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DOI
Abstract
This paper describes, for the first time, a simple and effective synthetic route for covalently bonding the chemiluminescence reagent, (4-[4-(dichloromethylsilanyl)-butyl]-4-methyl-2,2-bipyridyl)bis(2,2-bipyridyl)ruthenium(II) onto silica particles. The subsequent preparation of chemically regeneratable detection cells and their preliminary analytical evaluation with both sequential injection analysis and flow injection analysis are also reported. Unoptimised analytical figures of merit were established for standard solutions of codeine and sodium oxalate with detection limits calculated from three times the standard deviation of the blank signal, of 1 × 10–8 M and 3 × 10–7 M respectively. The chemically immobilised reagent exhibited some intriguing solvent and kinetic effects, which are also briefly discussed.
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Dissertation Note
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Copyright © 2002 Royal Society of Chemistry